Flume testing of passively adaptive composite tidal turbine blades under combined wave and current loading

The tidal energy industry is progressing rapidly, but there are still barriers to overcome to realise the commercial potential of this sector. Large magnitude and highly variable loads caused by waves acting on the turbine are of particular concern. Composite blades with in-built bend-twist elastic response may reduce these peak loads, by passively feathering with increasing thrust. This could decrease capital costs by lowering the design loads, and improve robustness through the mitigation of pitch mechanisms. In this study, the previous research is extended to examine the performance of bend-twist blades in combined wave–current flow, which will frequently be encountered in the field. A scaled 3 bladed turbine was tested in the flume at IFREMER with bend-twist composite blades and equivalent rigid blades, sequentially under current and co-directional wave–current cases. In agreement with previous research, when the turbine was operating in current alone at higher tip speed ratios the bend-twist blades reduced the mean thrust and power compared to the rigid blades. Under the specific wave–current condition tested the average loads were similar on both blade sets. Nevertheless, the bend-twist blades substantially reduced the magnitudes of the average thrust and torque fluctuations per wave cycle, by up to 10% and 14% respectively.     

Stochastic Analysis of Macrodispersion in a Semi‐Confined Aquifer

In this paper, the macroscopic dispersion resulting from one and twodimensional flows through a semiconfined aquifer with spatially variable hydraulic conductivity K which is represented by a stationary (statistically homogeneous) random process is analyzed using the spectral representation technique. Stochastic fluctuation equations of the steady flow and solute transport are solved to construct the macroscopic dispersive flux and evaluate the resulting macrodispersivity tensor in terms of the leakage factor and input covariances describing the hydraulic conductivity in a semiconfined aquifer bounded by a leaky layer above and an impervious stratum below. The macrodispersivity tensor is studied using some convenient forms of the log hydraulic conductivity process. The sensitivity of the resulting macrodispersivity to the input covariances is discussed along with the influence of the leakage factor for both one and twodimensional flows. It is found that the longitudinal macrodispersivities are increased due to the presence of leakage, while the transverse macrodispersivities are reduced due to leakage.     

External shock loading on a submerged fluid-filled cylindrical shell

The interaction between a submerged fluid-filled elastic circular cylindrical shell and an external shock wave is considered. The study focuses on the internal acoustic field. A linear formulation of the problem is considered. A semi-analytical solution is obtained and used to simulate the interaction. A variety of phenomena are observed in the internal fluid, including the reflection and focusing of the internal acoustic wave as well as the radiation into the fluid of elastic waves propagating in the shell. Throughout the paper, the results of numerical simulations are compared with available experimental data, and a good agreement is observed. The solution developed appears to be suitable for use as a benchmark. Engineering relevance of the phenomena observed is discussed.     

On drag, Strouhal number and vortex-street structure

A phenomenological model for the vortex-shedding process behind bluff cylindrical bodies is proposed. Relationships between Strouhal frequency St, drag coefficient c_D, Reynolds number Re and geometric wake parameters are obtained from mass conservation, momentum conservation in the transverse direction and energy considerations. For the first time, Roshko's (Technical Report TN 3169, NACA, US Government Printing Office, Washington DC, 1954) experimental discovery of vortex-street similarity behind different cylinders is analytically derived. In addition, the empirically obtained Strouhal-frequency laws of Roshko (Technical Report TN1191, NACA, US Government Printing Office, Washington DC, 1954) and Fey (Phys. fluids A 10 (1998) 1547) are also reproduced. Measurements of St and c_D including their Re dependency for flows around cylinders with circular, square, triangular, semi-circular and other cross sections agree favorably with the proposed model.     

Uniform persistence and flows near a closed positively invariant set

In this paper, the behavior of a continuous flow in the vicinity of a closed positively invariant subset in a metric space is investigated. The main theorem in this part in some sense generalizes previous results concerning classification of the flow near a compact invariant set in a locally compact metric space which was described by Ura-Kimura (1960) and Bhatia (1969). By applying the obtained main theorem, we are able to prove two persistence theorems. In the first one, several equivalent statements are established, which unify and generalize earlier results based on Liapunov-like functions and those about the equivalence of weak uniform persistence and uniform persistence. The second theorem generalizes the classical uniform persistence theorems based on analysis of the flow on the boundary by relaxing point dissipativity and invariance of the boundary. Several examples are given which show that our theorems will apply to a wider varity of ecological models.     

Analytical and numerical techniques to predict carbon nanotubes properties

In this paper, two different approaches for modeling the behaviour of carbon nanotubes are presented. The first method models carbon nanotubes as an inhomogeneous cylindrical network shell using the asymptotic homogenization method. Explicit formulae are derived representing Young’s and shear moduli of single-walled nanotubes in terms of pertinent material and geometric parameters. As an example, assuming certain values for these parameters, the Young’s modulus was found to be 1.71 TPa, while the shear modulus was 0.32 TPa. The second method is based on finite element models. The inter-atomic interactions due to covalent and non-covalent bonds are replaced by beam and spring elements, respectively, in the structural model. Correlations between classical molecular mechanics and structural mechanics are used to effectively model the physics governing the nanotubes. Finite element models are developed for single-, double- and multi-walled carbon nanotubes. The deformations from the finite element simulations are subsequently used to predict the elastic and shear moduli of the nanotubes. The variation of mechanical properties with tube diameter is investigated for both zig-zag and armchair configurations. Furthermore, the dependence of mechanical properties on the number of nanotubules in multi-walled structures is also examined. Based on the finite element model, the value for the elastic modulus varied from 0.9 to 1.05 TPa for single and 1.32 to 1.58 TPa for double/multi-walled nanotubes. The shear modulus was found to vary from 0.14 to 0.47 TPa for single-walled nanotubes and 0.37 to 0.62 for double/multi-walled nanotubes.     

Immobilized copper(II) on nitrogen‐rich polymer‐entrapped Fe3O4 nanoparticles: a highly loaded and magnetically recoverable catalyst for aqueous click chemistry

A heterogeneous magnetic copper catalyst was prepared via anchoring of copper sulfate onto multi‐layered poly(2‐dimethylaminoethyl acrylamide)‐coated magnetic nanoparticles and was characterized using various techniques. The catalyst was found to be active, effective and selective for one‐pot three‐component reaction of alkyl halide, sodium azide and alkyne, known as copper‐catalyzed click synthesis of 1,2,3‐triazoles. As little as 0.3 mol% of catalyst was found to be effective under the optimum conditions. The catalyst could also be recycled and reused up to seven times without significant loss of activity. Thermal stability, high loading level of copper on catalyst, broad diversity of alkyl/benzyl/allyl bromide/chloride and alkyl/aryl terminal alkynes without isolation of azide intermediate, and good to excellent yields of products make this procedure highly economical. Copyright © 2015 John Wiley & Sons, Ltd.     

Analysis of Carbamates as Fluorescent 1-Dimethylamino-naphthalene-5-sulfonate Esters

The fluorigenic labelling of several N-methyl carbamates is carried out using 1-dimethyl-aminonaphthalene-5-sulfonyl chloride (dansyl chloride). Prior to chromatography the carbamates are reacted in aqueous solution with the dansyl chloride. The derivative is extracted from the solution with n-hexane and subsequently spotted on a thin-layer plate for chromatography. For each N-methyl carbamate, two highly fluorescent spots are obtained. One is common to all N-methyl carbamates studied, whereas the other is characteristic of each individual carbamate. N.m.r. and infrared spectroscopic data indicate that the common spot is the methylamine derivative, and the second spot is the derivative from the phenyl moiety of each carbamate. The sensitivity of the method is less than one nanogram and has been successfully applied to the analysis of natural water samples.